Bis(2-methoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ2O,O′)manganate(II) dihydrate

Bis(2-methoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ2O,O′)manganate(II) dihydrate

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The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an Flight Socks MnII complex anion, a 2-methoxybenylammonium cation and a solvent water molecule.The MnII complex anion lies across an inversion center, and has a slightly distorted octahedral coordination environment for the MnII ion, formed by two bidentate dihydrogendiphosphate ligands and two water molecules.In the crystal, the components are linked by O—H.O and N—H.

O hydrogen bonds, forming layers parallel Toe downs to (100).An intramolecular N—H.O hydrogen bond is also observed.